What oxidation number do halogens generally have?

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Study for the Medical College Admission Test (MCAT). Test your chemistry skills with multiple-choice questions, each providing hints and explanations. Get exam ready!

Halogens, which include elements such as fluorine, chlorine, bromine, iodine, and astatine, typically have an oxidation number of -1 in their compounds. This behavior is due to their highly electronegative nature and their tendency to gain one electron to achieve a stable octet configuration, similar to the nearest noble gas.

For example, in compounds like sodium chloride (NaCl) and hydrogen chloride (HCl), chlorine shows an oxidation state of -1, as it gains one electron to bond with sodium or hydrogen, respectively. This is a consistent pattern observed across the halogen group under normal conditions, as they usually form anions by acquiring one electron.

Other oxidation states can occur under specific circumstances. For instance, in certain compounds, chlorine can exhibit positive oxidation states like +1, +3, +5, and +7 depending on what it is combined with, but these are less common than the -1 state. Therefore, recognizing that halogens typically hold an oxidation number of -1 allows for a better understanding of their reactivity and role in chemical reactions. This is why -1 is the most representative oxidation number for halogens in the majority of their compounds.